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Sewanee (Organometallic)

* Student contributor

“Synthesis and Reactivity of Potential Ampy-based Ruthenium(II) Catalyst for Amide Formation.” Amason, E. K.*; Rajabimoghadam, K.; Baughman, N N.;  Ghareeb, C. R*; Bourgeois, S. K.*; Keuk, C*; Manacsa, G*; Popp, B.V.; Garcia-Bosch, I.; Ferrence, G. M.; Joslin, E. E. Organometallics 2022, 41, 6, 686–697. https://doi.org/10.1021/acs.organomet.1c00444

“Synthesis and Characterization of the Complete Series of Chlorine Substituted Cobalt Acetylacetonate Complexes—[Co(acac)x(acac-Cl)3-x], x = 0-3.” Amason, E. K.*; Jones, M. H*; Keuk, C.*; Ferrence, G. M.; Joslin, E. E.; Bachman, R. E. Polyhedron, 2021, 201, 115188. https://doi.org/10.1016/j.poly.2021.115188

“Synthesis, characterization, X-ray crystallography analysis and cell viability study of (h6-p-cymene)Ru(NH2R)X2 (X = Cl, Br) derivatives.” McDarmont, S. L.*; Jones, M. H*; McMillen, C. D.; Smith, E. C.; Pienkos, J. A.; Joslin, E. E. Polyhedron, 2021, 200, 115130. https://doi.org/10.1016/j.poly.2021.115130

“Dehydrogenative Amide Synthesis Utilizing Ruthenium and Iron Catalysts via Traditional and Microwave techniques.”American Chemical Society UNI PRF.  Awarded: $55,000. Sept. 2018 – Aug. 2020. 

Sewanee (Pedagogical)

“Literature Discussion Classroom Activity based on Evidence of a homogeneous trinuclear Rh(I)-Cu(II)-Rh(I) catalyst for benzene C-H oxidative addition of styrene production (ACS Catal. 2021, 11, 5688-5702.) Lee, J.; Joslin, E.E., Webb, J.  Gunnoe, T. B. Virtual Inorganic Pedagogical Electronic Resource (VIPEr), March 2022. Literature Discussion Link

“Building a Steady Foundation through Equilibrium: Solution and Solid State Chemistry.” Miles, D. T.; Joslin, E. E. Journal of Chemical Education, J. Chem. Educ. 2021, 98, 3457-3465. https://doi.org/10.1021/acs.jchemed.1c00726

Postdoctoral Work (Metalloporphyrinoid)

“N-meso-methylation of a porphyrinoid complex: Activating the H-atom transfer capability of an inert ReV(O) corrolazine.” Joslin, E. E., Zaragoza, J. P. T., Seigler. M. A. Goldberg, D. P. Chem Commun., 2017, 53, 1961-1964. (DOI: 10.1039/C6CC09341H)

“The Influence of Peripheral Substituent Modification on PV, MnIII and MnV(O) Corrolazines: X-ray Crystallography, Electrochemical and Spectroscopic Properties, and HAT and OAT Reactivity.” Joslin, E. E.; Zaragoza, J. P. T., Baglia, R.A., Seigler. M. A. Goldberg, D. P. Inorg. Chem. 2016, 55 (17), 8646-8660) (DOI: 10.1021/acs.inorgchem.6b01219)

Graduate Work (Olefin Hydroarylation)

 “Studies of the Decomposition of the Ethylene Hydrophenylation Catalyst TpRu(CO)(NCMe)Ph.” Joslin, E. E.; McKeown, B. A.; Cundari, T. R.; Gunnoe, T. B. Journal of Organometallic Chemistry, 2017, 847, 289-293.

 “Hydrophenylation of Ethylene using a Cationic Ru(II) Catalyst: Comparison to a Neutral Ru(II) Catalyst.” Burgess, S. A.; Joslin, E. E.; Gunnoe, T. B.; Cundari, T.R.; Sabat, M; Myers, W.H. Chemical Science, 2014, 5, 4355-4366. (DOI: 10.1039/C4SC01665C )

 

“CH Activation of Pyrazolyl Ligands by Ru(II).” Joslin, E. E.; Quillian, B.; Gunnoe, T.B.; Cundari, T.R.; Sabat, M; Myers, W.H. Inorganic Chemistry, 2014, 53 (12), 6270–6279. (DOI: 10.1021/ic500811n)

 

“2,2,2-Tris(pyrazolyl)ethoxide (EpOX) Ruthenium (II) Complexes, (EpOX)RuCl(L)(L′): Synthesis, Structure and Reactivity.” Quillian, B.; Joslin, E. E.; McMullin, C. L.; Gunnoe, T. B.; Cundari, T. R.; Sabat, M.; Myers, W. H. Inorganic Chemisry, 2013, 52 (2), 1113–1121. (DOI: 10.1021/ic3024474)

“Catalytic Hydroarylation of Ethylene Using TpRu(L)(NCMe)Ph (L = 2,6,7-Trioxa-1-phosphabicyclo[2,2,1]heptane): Comparison to TpRu(L′)(NCMe)Ph Systems (L′ = CO, PMe3, P(pyr)3, or P(OCH2)3CEt).” Joslin, E. E.; McMullin, C. L.; Gunnoe, T. B.; Cundari, T. R.; Sabat, M.; Myers, W. H. Organometallics, 2012, 31(19), 6851-6860. (DOI: 10.1021/om300676e)

 

“Coordination Chemistry of 4-Methyl-2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane: Preparation and Characterization of Ru(II) Complexes.” Joslin, E. E.; McMullin, C. L.; Gunnoe, T. B.; Cundari, T. R.; Sabat, M.; Myers, W. H. Inorganic Chemistry, 2012, 51(8), 4791-4801. (DOI: 10.1021/ic300109b)

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